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系統識別號 U0026-0508201916181400
論文名稱(中文) 以近紫外光和可見光光芬頓法在含草酸水溶液中降解Orange G偶氮染料
論文名稱(英文) Degradation of Azo Dye Orange G by Oxalate Assisted-Photo-Fenton Method Using UV-A and Solar Light Irradiation
校院名稱 成功大學
系所名稱(中) 化學工程學系
系所名稱(英) Department of Chemical Engineering
學年度 107
學期 2
出版年 108
研究生(中文) 白安妮
研究生(英文) Inez Suciani
學號 N36067040
學位類別 碩士
語文別 英文
論文頁數 110頁
口試委員 指導教授-黃耀輝
口試委員-施育仁
口試委員-黃良銘
口試委員-廖志祥
中文關鍵字 none 
英文關鍵字 Orange-G  photo-Fenton process  photo-ferrioxalate process  Solar-LED  UV-A  decolorization  mineralization 
學科別分類
中文摘要 none
英文摘要 Among various kind of AOPs, Fenton’s reagent has been known to be an effective method for degrading organic compounds which can be enhanced by light irradiation and oxalic acid (OA) addition, to be photo-ferrioxalate system. This study aims to examine the use of photo-ferrioxalate process in degradation of Orange-G (OG) azo dye, which is used widely in textile industries, by using UV-A and Solar-LED irradiation.
In this study, 30 ppm of OG were treated using photo-ferrioxalate system. Operating variables included the initial iron concentration, initial H2O2 concentration, [OA]/[Fe3+] molar ratio, and light irradiation. The experimental results revealed that by using solar-LED light irradiation, complete color removal was possible, however only 47.50% TOC removal with TOC concentration of 9.04 ppm could be achieved after 420 min of reaction in the presence of 5 mg/L Fe3+, pHr= 5, 186 mg/L H2O2, and [OA]/[Fe3+] = 3. While by using UV-A light irradiation with the same parameter condition, higher TOC removal of 80.57% with TOC concentration of 4.16 ppm was obtained. Rate constant of OG degradation was calculated and it was found that OG decolorization followed a pseudo-first order kinetic model.
論文目次 Abstract I
Acknowledgement II
List of Tables VI
List of Figures VII
1. Introduction 1
1.1 Overview 1
1.2 Research Objective 3
2. Literature Review 5
2.1 Azo Dye 5
2.1.1 Reactive Black B (RBB) 6
2.1.2 Orange G (OG) 6
2.2 Degradation Pathway of Azo Dye 7
2.2.1 Reactive Black B (RBB) 8
2.2.2 Orange G (OG) 8
2.3 Advanced Oxidation Processes (AOPs) for treating dyes 13
2.4 Photocatalysis 14
2.5 Fenton and Fenton-like 16
2.6 Photo-Fenton 20
2.6.1 Photo-assisted Fenton oxidation with chelating agent 21
2.6.2 Ferric complex with oxalate ligand 23
2.6.3 Solar Photo-Fenton 27
2.7 Other reactions in Fenton and Photo-Fenton 28
2.7.1 Enhancement for hydroxyl radical reactions 28
2.7.2 Scavenger for hydroxyl radical reactions 30
2.8 Related Literatures 32
3. Experimental Method 34
3.1 Framework 34
3.2 Materials 35
3.3 Experimental Set-up 36
3.4 Experimental Procedure 37
3.5 Measurement and Analytical Methods 38
3.5.1 UV-Visible Absorbance 38
3.5.2 Ferrous ion concentration 39
3.5.3 H2O2 concentration 40
3.5.4 TOC (Total Organic Carbon) 41
3.6 Analytical Instruments 42
3.6.1 UV-Visible Spectrophotometer 42
3.6.2 Total Organic Carbon analyzer (TOC) 43
3.6.3 Gas Chromatography Mass Spectrometry (GC-MS) 43
4. Results and Discussions 45
4.1 Preliminary experiment 45
4.2 Stoichiometric reaction of OG and its absorbance measurement 48
4.3 OG degradation with photo-Fenton system (Fe2+/H2O2/UV-A) 52
4.3.1 Effect of initial concentration of Fe2+ 52
4.3.2 Effect of H2O2/OG mole ratio 55
4.3.3 Effect of different chelating agent addition 57
4.4 Comparison between photo-Fenton and photo-Fenton-like system 60
4.5 OG degradation with photo-Ferrioxalate (Fe3+/OA/H2O2/Light) 62
4.5.1 Photo-Fenton to Photo-Ferrioxalate 62
4.5.2 Kinetic model of photo-Ferrioxalate system 65
4.5.3 Effect of light irradiations 65
4.5.4 UVA-Photo-Ferrioxalate system 73
4.5.4.1 Effect of [OA]/[Fe3+] 73
4.5.4.2 Effect of [H2O2]/[OG] 77
4.5.5 Solar-Photo-Ferrioxalate system 81
4.5.5.1 Effect of [OA]/[Fe3+] 81
4.5.5.2 Effect of H2O2/OG mole ratio 85
4.6 OG degradation intermediates 89
5. Conclusions 93
References 94
Appendix 107
A.1. OG degradation intermediates 107
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